A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion

A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion

Dibenzo-7-phosphanorbornadiene Ph[subscript 3]PC(H)PA (1, A = C[subscript 14]H[subscript 10], anthracene) is reported here as a molecular precursor to phosphaethyne (HC≡P), produced together with anthracene and triphenylphosphine. HCP generated by thermolysis of 1 has been observed by molecular beam...

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Bibliographic Details
Main Authors:	Martin-Drumel, Marie-Aline, Hou, Gao-Lei, Wang, Xue-Bin, McCarthy, Michael C., Transue, Wesley, Velian, Alexandra, Nava, Matthew Jordan, Womack, Caroline C., Jiang, Jun, Field, Robert W, Cummins, Christopher C.
Other Authors:	Massachusetts Institute of Technology. Department of Chemistry
Format:	Article
Language:	en_US
Published:	American Chemical Society (ACS) 2017
Online Access:	http://hdl.handle.net/1721.1/107727 https://orcid.org/0000-0001-7445-5663 https://orcid.org/0000-0002-9239-7505 https://orcid.org/0000-0002-3526-3797 https://orcid.org/0000-0002-7609-4205 https://orcid.org/0000-0003-2568-3269

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