Fluorinated benzalkylsilane molecular rectifiers

We report on the synthesis and electrical properties of nine new alkylated silane self-assembled monolayers (SAMs) – (EtO)3Si(CH2)nN = CHPhX where n = 3 or 11 and X = 4-CF[subscript 3], 3,5-CF[subscript 3], 3-F-4-CF[subscript 3], 4-F, or 2,3,4,5,6-F, and explore their rectification behavior in relat...

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Bibliographic Details
Main Authors: Lamport, Zachary A., Broadnax, Angela D., Harrison, David, Barth, Katrina J., Mendenhall, Lee, Hamilton, Clayton T., Guthold, Martin, Thonhauser, Timo, Welker, Mark E., Jurchescu, Oana D.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: Nature Publishing Group 2017
Online Access:http://hdl.handle.net/1721.1/107785