Temperature dependence of acoustic vibrations of CdSe and CdSe–CdS core–shell nanocrystals measured by low-frequency Raman spectroscopy

We measure the temperature dependence of breathing-mode acoustic vibrations of semiconductor nanocrystals using low-frequency Raman spectroscopy. In CdSe core-only nanocrystals, the lowest-energy l = 0 mode red-shifts with increasing temperature by ∼5% between 77–300 K. Changes to the interatomic bo...

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Bibliographic Details
Main Authors: Mork, Anna Jolene, Lee, Elizabeth M., Tisdale, William
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering
Format: Article
Language:en_US
Published: Royal Society of Chemistry 2017
Online Access:http://hdl.handle.net/1721.1/107952
https://orcid.org/0000-0002-1872-6251
https://orcid.org/0000-0001-9143-3140
https://orcid.org/0000-0002-6615-5342