Temperature dependence of acoustic vibrations of CdSe and CdSe–CdS core–shell nanocrystals measured by low-frequency Raman spectroscopy
We measure the temperature dependence of breathing-mode acoustic vibrations of semiconductor nanocrystals using low-frequency Raman spectroscopy. In CdSe core-only nanocrystals, the lowest-energy l = 0 mode red-shifts with increasing temperature by ∼5% between 77–300 K. Changes to the interatomic bo...
Main Authors: | Mork, Anna Jolene, Lee, Elizabeth M., Tisdale, William |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemical Engineering |
Format: | Article |
Language: | en_US |
Published: |
Royal Society of Chemistry
2017
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Online Access: | http://hdl.handle.net/1721.1/107952 https://orcid.org/0000-0002-1872-6251 https://orcid.org/0000-0001-9143-3140 https://orcid.org/0000-0002-6615-5342 |
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