Composition and Structure of the Inorganic Core of Relaxed Intermediate

Activation of the diferrous center of the β2 (R2) subunit of the class 1a Escherichia coli ribonucleotide reductases by reaction with O2 followed by one-electron reduction yields a spin-coupled, paramagnetic Fe(III)/Fe(IV) intermediate, denoted X, whose identity has been sought by multiple investiga...

Full description

Bibliographic Details
Main Authors: Doan, Peter E., Shanmugam, Muralidharan, Hoffman, Brian M., Stubbe, JoAnne
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society 2017
Online Access:http://hdl.handle.net/1721.1/108075
https://orcid.org/0000-0001-8076-4489