Composition and Structure of the Inorganic Core of Relaxed Intermediate
Activation of the diferrous center of the β2 (R2) subunit of the class 1a Escherichia coli ribonucleotide reductases by reaction with O2 followed by one-electron reduction yields a spin-coupled, paramagnetic Fe(III)/Fe(IV) intermediate, denoted X, whose identity has been sought by multiple investiga...
Main Authors: | Doan, Peter E., Shanmugam, Muralidharan, Hoffman, Brian M., Stubbe, JoAnne |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society
2017
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Online Access: | http://hdl.handle.net/1721.1/108075 https://orcid.org/0000-0001-8076-4489 |
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