Synthesis of Alternating trans-AB Copolymers through Ring-Opening Metathesis Polymerization Initiated by Molybdenum Alkylidenes
Four alternating AB copolymers have been prepared through ring-opening metathesis polymerization (ROMP) with Mo(NR)(CHCMe₂Ph)[OCMe(CF₃)₂]₂ initiators (R = 2,6-Me₂C₆H₃ (1) or 2,6-i-Pr₂C₆H₃ (2)). The A:B monomer pairs copolymerized by 1 are cyclooctene (A):2,3-dicarbomethoxy-7-isopropylidenenorbornadi...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2017
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| Online Access: | http://hdl.handle.net/1721.1/108278 https://orcid.org/0000-0002-1788-4100 https://orcid.org/0000-0002-7405-6811 https://orcid.org/0000-0001-5827-3552 |