Molybdenum and Tungsten Alkylidene and Metallacyclobutane Complexes That Contain a Dianionic Biphenolate Pincer Ligand

Molybdenum imido alkylidene and tungsten oxo alkylidene complexes that contain a tridentate “pincer” [ONO]²⁻ ligand have been prepared and treated with ethylene to give unsubstituted metallacyclobutane complexes that have a 16e count. Both Mo and W metallacyclobutane complexes exchange C₂D₄ into the...

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Bibliographic Details
Main Authors: Sues, Peter V. E., John, Jeremy M, Schrock, Richard Royce, Mueller, Peter
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2017
Online Access:http://hdl.handle.net/1721.1/108288
https://orcid.org/0000-0002-3975-119X
https://orcid.org/0000-0002-7405-6811
https://orcid.org/0000-0001-5827-3552