¹⁵N and ¹H Solid-State NMR Investigation of a Canonical Low-Barrier Hydrogen-Bond Compound: 1,8-Bis(dimethylamino)naphthalene
Strong or low-barrier hydrogen bonds have often been proposed in proteins to explain enzyme catalysis and proton-transfer reactions. So far ¹H chemical shifts and scalar couplings have been used as the main NMR spectroscopic signatures for strong H-bonds. In this work, we report simultaneous measure...
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Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2017
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Online Access: | http://hdl.handle.net/1721.1/110373 |