Highly Regioselective Indoline Synthesis under Nickel/Photoredox Dual Catalysis
Nickel/photoredox catalysis is used to synthesize indolines in one step from iodoacetanilides and alkenes. Very high regioselectivity for 3-substituted indoline products is obtained for both aliphatic and styrenyl olefins. Mechanistic investigations indicate that oxidation to Ni(III) is necessary to...
Main Authors: | Tasker, Sarah Zinnen, Jamison, Timothy F |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2017
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Online Access: | http://hdl.handle.net/1721.1/110421 https://orcid.org/0000-0003-2315-6983 https://orcid.org/0000-0002-8601-7799 |
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