Kinetics of Hydrogen Atom Abstraction from Substrate by an Active Site Thiyl Radical in Ribonucleotide Reductase
Ribonucleotide reductases (RNRs) catalyze the conversion of nucleotides to deoxynucleotides in all organisms. Active E. coli class Ia RNR is an α[subscript 2]β[subscript 2] complex that undergoes reversible, long-range proton-coupled electron transfer (PCET) over a pathway of redox active amino acid...
| Main Authors: | , , , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2017
|
| Online Access: | http://hdl.handle.net/1721.1/110443 https://orcid.org/0000-0002-0137-3234 https://orcid.org/0000-0001-8076-4489 https://orcid.org/0000-0002-8683-3593 |