Water Exchange at a Hydrated Platinum Electrode is Rare and Collective

We use molecular dynamics simulations to study the exchange kinetics of water molecules at a model metal electrode surface–exchange between water molecules in the bulk liquid and water molecules bound to the metal. This process is a rare event, with a mean residence time of a bound water of ∼40 ns f...

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Bibliographic Details
Main Authors: Limmer, David T., Willard, Adam P., Madden, Paul A., Chandler, David
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2017
Online Access:http://hdl.handle.net/1721.1/110450