Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes

A copper-catalyzed, chemoselective hydrometalation process enables the use of simple allenes as allylmetal nucleophile surrogates in imine allylation reactions. By modulating the nitrogen-protecting group, either highly branched- or linear-selective addition can be achieved from the same allene. Bot...

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Bibliographic Details
Main Authors: Liu, Richard Y., Yang, Yang, Buchwald, Stephen L., Liu, Richard, Buchwald, Stephen Leffler
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: Wiley-Blackwell 2018
Online Access:http://hdl.handle.net/1721.1/113041
https://orcid.org/0000-0003-3875-4775