Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes
A copper-catalyzed, chemoselective hydrometalation process enables the use of simple allenes as allylmetal nucleophile surrogates in imine allylation reactions. By modulating the nitrogen-protecting group, either highly branched- or linear-selective addition can be achieved from the same allene. Bot...
Main Authors: | Liu, Richard Y., Yang, Yang, Buchwald, Stephen L., Liu, Richard, Buchwald, Stephen Leffler |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Published: |
Wiley-Blackwell
2018
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Online Access: | http://hdl.handle.net/1721.1/113041 https://orcid.org/0000-0003-3875-4775 |
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