Dihydrogen Tetrametaphosphate, [P[subscript 4]O][subscript 12]H[subscript 2]][superscript 2] –: Synthesis, Solubilization in Organic Media, Preparation of its Anhydride [P[subscript 4]O[subscript 11]][superscript 2] – and Acidic Methyl Ester, and Conversion to Tetrametaphosphate Metal Complexes via Protonolysis

Dihydrogen tetrametaphosphate [P[subscript 4]O[subscript 12]H[subscript 2]] [superscript 2]- (1) can now be synthesized and isolated as its PPN salt ([PPN] + = [N(PPh[subscript 3])[subscript 2]][superscript +]) via treatment of [PPN][subscript 4 ][P[subscript 4]O[subscript 12]] with trifluoroacetic...

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Bibliographic Details
Main Authors: Marino, Nadia, Jiang, Yanfeng, Chakarawet, Khetpakorn, Kohout, Andrea Laura, Nava, Matthew Jordan, Cummins, Christopher C
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/113228
https://orcid.org/0000-0003-3497-181X
https://orcid.org/0000-0002-9239-7505
https://orcid.org/0000-0003-2568-3269