Multi-electron reactivity of a cofacial di-tin(I) cryptand: partial reduction of sulfur and selenium and reversible generation of S[subscript 3][superscript ˙−]
Cofacial bimetallic tin(ii) ([Sn[subscript 2](mBDCA-5t)][superscript 2−], 1) and lead(ii) ([Pb[subscript 2](mBDCA-5t)][superscrip 2−], 2) complexes have been prepared by hexadeprotonation of hexacarboxamide cryptand mBDCA-5t-H[subscript 6] together with double Sn(ii) or Pb(ii) insertion. Reaction of...
| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Published: |
Royal Society of Chemistry (RSC)
2018
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| Online Access: | http://hdl.handle.net/1721.1/113233 https://orcid.org/0000-0001-9783-907X https://orcid.org/0000-0003-2568-3269 |