A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO₂/ethylene Coupling

A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO₂/ethylene Coupling

A family of cis-macrocyclic diphosphines was prepared in just three steps from white phosphorus and commercial materials using a modular synthetic approach. Alkylation of bicyclic diphosphane 3,4,8,9-tetramethyl-1,6-diphosphabicyclo(4.4.0)deca-3,8-diene, or P₂(dmb)₂ , produced phosphino-phosphonium...

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Bibliografiska uppgifter
Huvudupphovsmän: Beetstra, Dirk, Al-Nezari, Abdulaziz, Al-Bahily, Khalid, Knopf, Ioana, Tofan, Daniel, Cummins, Christopher C
Övriga upphovsmän: Massachusetts Institute of Technology. Department of Chemistry
Materialtyp: Artikel
Publicerad: Royal Society of Chemistry (RSC) 2018
Länkar:http://hdl.handle.net/1721.1/113248
https://orcid.org/0000-0002-1335-9755
https://orcid.org/0000-0003-2568-3269

Internet

http://hdl.handle.net/1721.1/113248
https://orcid.org/0000-0002-1335-9755
https://orcid.org/0000-0003-2568-3269

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