On the Incompatibility of lithium–O₂ Battery Technology with CO₂

When solubilized in a hexacarboxamide cryptand anion receptor, the peroxide dianion reacts rapidly with CO₂ in polar aprotic organic media to produce hydroperoxycarbonate (HOOCO₂- ) and peroxydicarbonate (-O₂ COOCO₂-). Peroxydicarbonate is subject to thermal fragmentation into two equivalents of the...

Полное описание

Библиографические подробности
Главные авторы: Chow, Gary K., Lopez, Nazario, Britt, David R., Nocera, Daniel G., Zhang, Shiyu, Nava, Matthew Jordan, Wu, Gang, Cummins, Christopher C
Другие авторы: Massachusetts Institute of Technology. Department of Chemistry
Формат: Статья
Опубликовано: Royal Society of Chemistry (RSC) 2018
Online-ссылка:http://hdl.handle.net/1721.1/113277
https://orcid.org/0000-0002-9239-7505
https://orcid.org/0000-0003-2568-3269