On the Incompatibility of lithium–O₂ Battery Technology with CO₂

On the Incompatibility of lithium–O₂ Battery Technology with CO₂

When solubilized in a hexacarboxamide cryptand anion receptor, the peroxide dianion reacts rapidly with CO₂ in polar aprotic organic media to produce hydroperoxycarbonate (HOOCO₂- ) and peroxydicarbonate (-O₂ COOCO₂-). Peroxydicarbonate is subject to thermal fragmentation into two equivalents of the...

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Bibliographic Details
Main Authors: Chow, Gary K., Lopez, Nazario, Britt, David R., Nocera, Daniel G., Zhang, Shiyu, Nava, Matthew Jordan, Wu, Gang, Cummins, Christopher C
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: Royal Society of Chemistry (RSC) 2018
Online Access:http://hdl.handle.net/1721.1/113277
https://orcid.org/0000-0002-9239-7505
https://orcid.org/0000-0003-2568-3269

Internet

http://hdl.handle.net/1721.1/113277
https://orcid.org/0000-0002-9239-7505
https://orcid.org/0000-0003-2568-3269

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