Spontaneous and Selective Formation of HSNO, a Crucial Intermediate Linking H₂S and Nitroso Chemistries

Thionitrous acid (HSNO), a potential key intermediate in biological signaling pathways, has been proposed to link NO and H₂S biochemistries, but its existence and stability in vivo remain controversial. We establish that HSNO is spontaneously formed in high concentration when NO and H₂S gases are mi...

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Bibliographic Details
Main Authors: Martin-Drumel, Marie-Aline, Lopez, Christopher A., Crabtree, Kyle N., Nguyen, Thanh L., Thorwirth, Sven, Stanton, John F., McCarthy, Michael C., Nava, Matthew Jordan, Womack, Caroline C., Cummins, Christopher C
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/113278
https://orcid.org/0000-0002-9239-7505
https://orcid.org/0000-0003-2568-3269