Biphenyl-Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4+1] Annulations To Form Functionalized Cyclopentenes

Biphenyl-Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4+1] Annulations To Form Functionalized Cyclopentenes

Because of the frequent occurrence of cyclopentane subunits in bioactive compounds, the development of efficient catalytic asymmetric methods for their synthesis is an important objective. Introduced herein is a new family of chiral nucleophilic catalysts, biphenyl-derived phosphepines, and we apply...

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Bibliographic Details
Main Authors: Ziegler, Daniel Todd, Riesgo Canal, Lorena, Ikeda, Takuya, Fujiwara, Yuji, Fu, Gregory C
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: Wiley-Blackwell 2018
Online Access:http://hdl.handle.net/1721.1/113310

Internet

http://hdl.handle.net/1721.1/113310

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