Interrogating the Lewis Acidity of Metal Sites in Beta Zeolites with ¹⁵N Pyridine Adsorption Coupled with MAS NMR Spectroscopy

The Lewis acidity of isolated framework metal sites in Beta zeolites was characterized with ¹⁵N isotopically labeled pyridine adsorption coupled with magic-angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy. The ¹⁵N chemical shift of adsorbed pyridine was found to scale with the acid c...

Cur síos iomlán

Sonraí bibleagrafaíochta
Príomhchruthaitheoirí: Gunther, William Robert, Michaelis, Vladimir K., Griffin, Robert Guy, Román-Leshkov, Yuriy
Rannpháirtithe: Massachusetts Institute of Technology. Department of Chemical Engineering
Formáid: Alt
Foilsithe / Cruthaithe: American Chemical Society (ACS) 2018
Rochtain ar líne:http://hdl.handle.net/1721.1/113314
https://orcid.org/0000-0002-6708-7660
https://orcid.org/0000-0003-1589-832X