Interrogating the Lewis Acidity of Metal Sites in Beta Zeolites with ¹⁵N Pyridine Adsorption Coupled with MAS NMR Spectroscopy
The Lewis acidity of isolated framework metal sites in Beta zeolites was characterized with ¹⁵N isotopically labeled pyridine adsorption coupled with magic-angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy. The ¹⁵N chemical shift of adsorbed pyridine was found to scale with the acid c...
Main Authors: | Gunther, William Robert, Michaelis, Vladimir K., Griffin, Robert Guy, Román-Leshkov, Yuriy |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemical Engineering |
Format: | Article |
Published: |
American Chemical Society (ACS)
2018
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Online Access: | http://hdl.handle.net/1721.1/113314 https://orcid.org/0000-0002-6708-7660 https://orcid.org/0000-0003-1589-832X |
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