Synthesis and Utilization of Nitroalkyne Equivalents in Batch and Continuous Flow

We report a method for overcoming the low stability of nitroalkynes through the development of nitrated vinyl silyltriflate equivalents. Because of their instability, nitroalkynes have only rarely been utilized in synthesis. The reactivity of these silyltriflates, which are prepared in situ, is exem...

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Bibliographic Details
Main Authors: Morse, Peter D, Jamison, Timothy F
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: Wiley Blackwell 2018
Online Access:http://hdl.handle.net/1721.1/113322
https://orcid.org/0000-0002-8601-7799