Gd(iii) and Mn(ii) Complexes for Dynamic Nuclear Polarization: Small Molecular Chelate Polarizing Agents and Applications with Site-Directed Spin Labeling of Proteins

Gd(iii) and Mn(ii) Complexes for Dynamic Nuclear Polarization: Small Molecular Chelate Polarizing Agents and Applications with Site-Directed Spin Labeling of Proteins

We investigate complexes of two paramagnetic metal ions Gd³⁺ and Mn²⁺ to serve as polarizing agents for solid-state dynamic nuclear polarization (DNP) of ¹H, ¹³C, and ¹⁵N at magnetic fields of 5, 9.4, and 14.1 T. Both ions are half-integer high-spin systems with a zero-field splitting and therefore...

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Bibliographic Details
Main Authors: Kaushik, Monu, Bahrenberg, Thorsten, Caporini, Marc A., Heiliger, Jörg, Schwalbe, Harald, Can, Thach V, Silvers, Robert Paul Georg, Griffin, Robert Guy, Corzilius, Bjorn, Silvers, Robert, 1968-, Smith, Albert A.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: Royal Society of Chemistry (RSC) 2018
Online Access:http://hdl.handle.net/1721.1/113324
https://orcid.org/0000-0001-9092-612X
https://orcid.org/0000-0003-1589-832X

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http://hdl.handle.net/1721.1/113324
https://orcid.org/0000-0001-9092-612X
https://orcid.org/0000-0003-1589-832X

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