Synthesis of Cis,syndiotactic A-alt-B Copolymers from Two Enantiomerically Pure Trans-2,3-Disubstituted-5,6-Norbornenes

Cis, syndiotactic A-alt-B copolymers, where A and B are two enantiomerically pure trans-2,3-disubstituted- 5,6-norbornenes with "opposite" chiralities, can be prepared with stereogenic-at-metal initiators of the type M(NR)- (CHR')(OR")(pyrrolide). Formation of a high percentage o...

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Bibliographic Details
Main Authors: Jang, Eun Sil, John, Jeremy M, Schrock, Richard Royce
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/113613
https://orcid.org/0000-0002-7405-6811
https://orcid.org/0000-0001-5827-3552