Convergent and Biomimetic Enantioselective Total Synthesis of (−)-Communesin F
The first biomimetic enantioselective total synthesis of (-)-communesin F based on a late-stage heterodimerization and aminal exchange is described. Our synthesis features the expedient diazene-directed assembly of two advanced fragments to secure the congested C3a-C3a′ linkage in three steps, follo...
Main Authors: | Lathrop, Stephen, Pompeo, Matthew M, Chang, Wen-Tau, Movassaghi, Mohammad |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Published: |
American Chemical Society (ACS)
2018
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Online Access: | http://hdl.handle.net/1721.1/114840 https://orcid.org/0000-0001-7761-085X https://orcid.org/0000-0001-5955-7653 https://orcid.org/0000-0003-3080-1063 |
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