Donor-Dependent Kinetics of Interfacial Proton-Coupled Electron Transfer

The effect of the proton donor on the kinetics of interfacial concerted proton–electron transfer (CPET) to polycrystalline Au was probed indirectly by studying the rate of hydrogen evolution from trialkylammonium donors with different steric profiles, but the same pK[subscript a]. Detailed kinetic s...

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Bibliographic Details
Main Authors: Jackson, Megan, Surendranath, Yogesh
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/114889
https://orcid.org/0000-0002-7978-5212
https://orcid.org/0000-0003-1016-3420