Selective Dimerization of Propylene with Ni-MFU-4

Selective Dimerization of Propylene with Ni-MFU-4

We report the selective dimerization of propylene to branched hexenes using Ni-MFU-4l, a solid catalyst prepared by cation exchange. Analysis of the resulting product distribution demonstrates that the selectivity arises from 2,1-insertion and slow product reinsertion, mechanistic features reproduce...

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Bibliographic Details
Main Authors: Wu, Zhenwei, Zhang, Guanghui, Miller, Jeffrey T., Comito, Robert J, Metzger, Eric Daniel, Hendon, Christopher H, Dinca, Mircea
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/114955
https://orcid.org/0000-0003-1298-2876
https://orcid.org/0000-0001-6597-1981
https://orcid.org/0000-0002-1262-1264

Internet

http://hdl.handle.net/1721.1/114955
https://orcid.org/0000-0003-1298-2876
https://orcid.org/0000-0001-6597-1981
https://orcid.org/0000-0002-1262-1264

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