Selective Dimerization of Propylene with Ni-MFU-4
We report the selective dimerization of propylene to branched hexenes using Ni-MFU-4l, a solid catalyst prepared by cation exchange. Analysis of the resulting product distribution demonstrates that the selectivity arises from 2,1-insertion and slow product reinsertion, mechanistic features reproduce...
Main Authors: | Wu, Zhenwei, Zhang, Guanghui, Miller, Jeffrey T., Comito, Robert J, Metzger, Eric Daniel, Hendon, Christopher H, Dinca, Mircea |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2018
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Online Access: | http://hdl.handle.net/1721.1/114955 https://orcid.org/0000-0003-1298-2876 https://orcid.org/0000-0001-6597-1981 https://orcid.org/0000-0002-1262-1264 |
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