Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene

Molybdenum complexes with the general formula Mo(NR)(CHR′)(OR″)(Cl)(MeCN) (R = t-Bu or 1-adamantyl; OR″ = a 2,6-terphenoxide) recently have been found to be highly active catalysts for cross-metathesis reactions between Z-internal olefins and Z-1,2-dichloroethylene or Z-(CF₃)CH═CH(CF₃). In this pape...

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Bibliographic Details
Main Authors: Hoveyda, Amir, Lam, Jonathan K, Zhu, Congqing, Bukhryakov, Konstantin, Mueller, Peter, Schrock, Richard Royce
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/115116
https://orcid.org/0000-0003-1913-7173
https://orcid.org/0000-0001-6530-3852
https://orcid.org/0000-0001-5827-3552