The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels

The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels

The structure-directing role of the inorganic secondary building unit (SBU) is key for determining the topology of metal–organic frameworks (MOFs). Here we show that organic building units relying on strong π interactions that are energetically competitive with the formation of common inorganic SBUs...

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Bibliographic Details
Main Authors: Fielding, Alistair J., Walsh, Aron, O’Keeffe, Michael, Park, Sarah Sunah, Hendon, Christopher H, Dinca, Mircea
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/115120
https://orcid.org/0000-0002-7837-8412
https://orcid.org/0000-0002-1262-1264

Internet

http://hdl.handle.net/1721.1/115120
https://orcid.org/0000-0002-7837-8412
https://orcid.org/0000-0002-1262-1264

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