The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels
The structure-directing role of the inorganic secondary building unit (SBU) is key for determining the topology of metal–organic frameworks (MOFs). Here we show that organic building units relying on strong π interactions that are energetically competitive with the formation of common inorganic SBUs...
| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
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American Chemical Society (ACS)
2018
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| Online Access: | http://hdl.handle.net/1721.1/115120 https://orcid.org/0000-0002-7837-8412 https://orcid.org/0000-0002-1262-1264 |
| _version_ | 1811085708304056320 |
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| author | Fielding, Alistair J. Walsh, Aron O’Keeffe, Michael Park, Sarah Sunah Hendon, Christopher H Dinca, Mircea |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Fielding, Alistair J. Walsh, Aron O’Keeffe, Michael Park, Sarah Sunah Hendon, Christopher H Dinca, Mircea |
| author_sort | Fielding, Alistair J. |
| collection | MIT |
| description | The structure-directing role of the inorganic secondary building unit (SBU) is key for determining the topology of metal–organic frameworks (MOFs). Here we show that organic building units relying on strong π interactions that are energetically competitive with the formation of common inorganic SBUs can also play a role in defining the topology. We demonstrate the importance of the organic SBU in the formation of Mg₂H₆(H₃O)(TTFTB)₃(MIT-25), a mesoporous MOF with the new ssp topology. A delocalized electronic hole is critical in the stabilization of the TTF triad organic SBUs and exemplifies a design principle for future MOF synthesis. |
| first_indexed | 2024-09-23T13:14:19Z |
| format | Article |
| id | mit-1721.1/115120 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T13:14:19Z |
| publishDate | 2018 |
| publisher | American Chemical Society (ACS) |
| record_format | dspace |
| spelling | mit-1721.1/1151202022-09-28T12:51:44Z The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels Fielding, Alistair J. Walsh, Aron O’Keeffe, Michael Park, Sarah Sunah Hendon, Christopher H Dinca, Mircea Massachusetts Institute of Technology. Department of Chemistry Dinca, Mircea Park, Sarah Sunah Hendon, Christopher H Dinca, Mircea The structure-directing role of the inorganic secondary building unit (SBU) is key for determining the topology of metal–organic frameworks (MOFs). Here we show that organic building units relying on strong π interactions that are energetically competitive with the formation of common inorganic SBUs can also play a role in defining the topology. We demonstrate the importance of the organic SBU in the formation of Mg₂H₆(H₃O)(TTFTB)₃(MIT-25), a mesoporous MOF with the new ssp topology. A delocalized electronic hole is critical in the stabilization of the TTF triad organic SBUs and exemplifies a design principle for future MOF synthesis. National Science Foundation (U.S.) (Award 1122374) 2018-05-01T14:06:51Z 2018-05-01T14:06:51Z 2017-03 2016-12 Article http://purl.org/eprint/type/JournalArticle 0002-7863 1520-5126 http://hdl.handle.net/1721.1/115120 Park, Sarah S. et al. “The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels.” Journal of the American Chemical Society 139, 10 (March 2017): 3619–3622 © 2017 American Chemical Society https://orcid.org/0000-0002-7837-8412 https://orcid.org/0000-0002-1262-1264 en_US http://dx.doi.org/10.1021/jacs.6b13176 Journal of the American Chemical Society Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) Prof. Dinca via Erja Kajosalo |
| spellingShingle | Fielding, Alistair J. Walsh, Aron O’Keeffe, Michael Park, Sarah Sunah Hendon, Christopher H Dinca, Mircea The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels |
| title | The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels |
| title_full | The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels |
| title_fullStr | The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels |
| title_full_unstemmed | The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels |
| title_short | The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels |
| title_sort | organic secondary building unit strong intermolecular π interactions define topology in mit 25 a mesoporous mof with proton replete channels |
| url | http://hdl.handle.net/1721.1/115120 https://orcid.org/0000-0002-7837-8412 https://orcid.org/0000-0002-1262-1264 |
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