The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels
The structure-directing role of the inorganic secondary building unit (SBU) is key for determining the topology of metal–organic frameworks (MOFs). Here we show that organic building units relying on strong π interactions that are energetically competitive with the formation of common inorganic SBUs...
Main Authors: | Fielding, Alistair J., Walsh, Aron, O’Keeffe, Michael, Park, Sarah Sunah, Hendon, Christopher H, Dinca, Mircea |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2018
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Online Access: | http://hdl.handle.net/1721.1/115120 https://orcid.org/0000-0002-7837-8412 https://orcid.org/0000-0002-1262-1264 |
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