Reversing the Native Aerobic Oxidation Reactivity of Graphitic Carbon: Heterogeneous Metal-Free Alkene Hydrogenation

Commercially available carbon blacks serve as effective metal-free catalysts for the selective hydrogenation of carbon–carbon multiple bonds under aerobic conditions using hydrazine as the terminal reductant. The reaction, which proceeds through a putative diimide intermediate, displays high toleran...

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Bibliographic Details
Main Authors: Murray, Alexander T, Surendranath, Yogesh
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/115122
https://orcid.org/0000-0003-1016-3420