Reversing the Native Aerobic Oxidation Reactivity of Graphitic Carbon: Heterogeneous Metal-Free Alkene Hydrogenation
Commercially available carbon blacks serve as effective metal-free catalysts for the selective hydrogenation of carbon–carbon multiple bonds under aerobic conditions using hydrazine as the terminal reductant. The reaction, which proceeds through a putative diimide intermediate, displays high toleran...
Main Authors: | Murray, Alexander T, Surendranath, Yogesh |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2018
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Online Access: | http://hdl.handle.net/1721.1/115122 https://orcid.org/0000-0003-1016-3420 |
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