Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes
[Ar₂N₃]Mo(N)(O-t-Bu), which contains the conformationally rigid pyridine-based diamido ligand, [2,6-(ArNCH₂)₂NC₅H₃]²– (Ar = 2,6-diisopropylphenyl), can be prepared from H₂[Ar₂N₃], butyllithium, and (t-BuO)₃Mo(N). [Ar₂N₃]Mo(N)(O-t-Bu) serves as a catalyst or precursor for the catalytic reduction of m...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2018
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| Online Access: | http://hdl.handle.net/1721.1/116567 https://orcid.org/0000-0003-2933-8665 https://orcid.org/0000-0003-1654-1146 https://orcid.org/0000-0001-5827-3552 |