Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds

Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds

Dibenzo-7-phosphanorbornadiene compounds, RPA (A = C₁₄H₁₀ or anthracene), are investigated as phosphinidene sources upon thermally induced (70–90 °C) anthracene elimination. Analysis of substituent effects reveals that π-donating dialkylamide groups are paramount to successful phosphinidene transfer...

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Bibliographic Details
Main Authors: García-Iriepa, Cristina, Temprado, Manuel, Transue, Wesley, Velian, Alexandra, Nava, Matthew Jordan, Cummins, Christopher C
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/117205
https://orcid.org/0000-0001-7445-5663
https://orcid.org/0000-0002-9239-7505
https://orcid.org/0000-0003-2568-3269

Internet

http://hdl.handle.net/1721.1/117205
https://orcid.org/0000-0001-7445-5663
https://orcid.org/0000-0002-9239-7505
https://orcid.org/0000-0003-2568-3269

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