Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds
Dibenzo-7-phosphanorbornadiene compounds, RPA (A = C₁₄H₁₀ or anthracene), are investigated as phosphinidene sources upon thermally induced (70–90 °C) anthracene elimination. Analysis of substituent effects reveals that π-donating dialkylamide groups are paramount to successful phosphinidene transfer...
| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2018
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| Online Access: | http://hdl.handle.net/1721.1/117205 https://orcid.org/0000-0001-7445-5663 https://orcid.org/0000-0002-9239-7505 https://orcid.org/0000-0003-2568-3269 |