Interplay of phase boundary anisotropy and electro-auto-catalytic surface reactions on the lithium intercalation dynamics in Li[subscript X]FePO[subscript 4] plateletlike nanoparticles

Experiments on single crystal Lip[subscript X]FePO[subscript 4] nanoparticles indicate rich nonequilibrium phase behavior, such as suppression of phase separation at high lithiation rates, striped patterns of coherent phase boundaries, and nucleation by binary-solid surface wetting and intercalation...

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Bibliographic Details
Main Authors: Di Leo, Claudio V., Bai, Peng, Nadkarni, Neel, Rejovitsky, Elisha, Fraggedakis, Dimitrios, Smith, Raymond Barrett, Bazant, Martin Z
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering
Format: Article
Language:English
Published: American Physical Society 2018
Online Access:http://hdl.handle.net/1721.1/117400
https://orcid.org/0000-0003-2421-6781
https://orcid.org/0000-0002-8200-4501