Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu)

Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu)

The two-dimensionally connected metal–organic frameworks (MOFs) Ni₃(HIB)₂ and Cu₃(HIB)₂ (HIB = hexaiminobenzene) are bulk electrical conductors and exhibit ultraviolet-photoelectron spectroscopy (UPS) signatures expected of metallic solids. Electronic band structure calculations confirm that in both...

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Bibliographic Details
Main Authors: Gul, Sheraz, Yano, Junko, Stach, Eric A., Dou, Jinhu, Sun, Lei, Ge, Yicong, Li, Wenbin, Hendon, Christopher H, Li, Ju, Dinca, Mircea
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/118371
https://orcid.org/0000-0002-5645-7531
https://orcid.org/0000-0002-7841-8058
https://orcid.org/0000-0002-1262-1264

Internet

http://hdl.handle.net/1721.1/118371
https://orcid.org/0000-0002-5645-7531
https://orcid.org/0000-0002-7841-8058
https://orcid.org/0000-0002-1262-1264

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