Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu)
The two-dimensionally connected metal–organic frameworks (MOFs) Ni₃(HIB)₂ and Cu₃(HIB)₂ (HIB = hexaiminobenzene) are bulk electrical conductors and exhibit ultraviolet-photoelectron spectroscopy (UPS) signatures expected of metallic solids. Electronic band structure calculations confirm that in both...
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| Format: | Article |
| Language: | en_US |
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American Chemical Society (ACS)
2018
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| Online Access: | http://hdl.handle.net/1721.1/118371 https://orcid.org/0000-0002-5645-7531 https://orcid.org/0000-0002-7841-8058 https://orcid.org/0000-0002-1262-1264 |
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| author | Gul, Sheraz Yano, Junko Stach, Eric A. Dou, Jinhu Sun, Lei Ge, Yicong Li, Wenbin Hendon, Christopher H Li, Ju Dinca, Mircea |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Gul, Sheraz Yano, Junko Stach, Eric A. Dou, Jinhu Sun, Lei Ge, Yicong Li, Wenbin Hendon, Christopher H Li, Ju Dinca, Mircea |
| author_sort | Gul, Sheraz |
| collection | MIT |
| description | The two-dimensionally connected metal–organic frameworks (MOFs) Ni₃(HIB)₂ and Cu₃(HIB)₂ (HIB = hexaiminobenzene) are bulk electrical conductors and exhibit ultraviolet-photoelectron spectroscopy (UPS) signatures expected of metallic solids. Electronic band structure calculations confirm that in both materials the Fermi energy lies in a partially filled delocalized band. Together with additional structural characterization and microscopy data, these results represent the first report of metallic behavior and permanent porosity coexisting within a metal–organic framework. |
| first_indexed | 2024-09-23T11:34:07Z |
| format | Article |
| id | mit-1721.1/118371 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T11:34:07Z |
| publishDate | 2018 |
| publisher | American Chemical Society (ACS) |
| record_format | dspace |
| spelling | mit-1721.1/1183712022-09-27T20:24:10Z Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu) Gul, Sheraz Yano, Junko Stach, Eric A. Dou, Jinhu Sun, Lei Ge, Yicong Li, Wenbin Hendon, Christopher H Li, Ju Dinca, Mircea Massachusetts Institute of Technology. Department of Chemistry Massachusetts Institute of Technology. Department of Materials Science and Engineering Massachusetts Institute of Technology. Department of Nuclear Science and Engineering Massachusetts Institute of Technology. Research Laboratory of Electronics Dinca, Mircea Dou, Jinhu Sun, Lei Ge, Yicong Li, Wenbin Hendon, Christopher H Li, Ju Dinca, Mircea The two-dimensionally connected metal–organic frameworks (MOFs) Ni₃(HIB)₂ and Cu₃(HIB)₂ (HIB = hexaiminobenzene) are bulk electrical conductors and exhibit ultraviolet-photoelectron spectroscopy (UPS) signatures expected of metallic solids. Electronic band structure calculations confirm that in both materials the Fermi energy lies in a partially filled delocalized band. Together with additional structural characterization and microscopy data, these results represent the first report of metallic behavior and permanent porosity coexisting within a metal–organic framework. United States. Army Research Office (Grant W911NF-17-1-0174) United States. Department of Energy. Office of Basic Energy Sciences (Award DE-SC0001088) 2018-10-05T15:31:26Z 2018-10-05T15:31:26Z 2017-09 2017-07 Article http://purl.org/eprint/type/JournalArticle 0002-7863 1520-5126 http://hdl.handle.net/1721.1/118371 Dou, Jin-Hu, Lei Sun et al. “Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu).” Journal of the American Chemical Society 139, 39 (September 2017): 13608–13611 © 2017 American Chemical Society https://orcid.org/0000-0002-5645-7531 https://orcid.org/0000-0002-7841-8058 https://orcid.org/0000-0002-1262-1264 en_US http://dx.doi.org/10.1021/jacs.7b07234 Journal of the American Chemical Society Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) Prof. Dinca via Erja Kajosalo |
| spellingShingle | Gul, Sheraz Yano, Junko Stach, Eric A. Dou, Jinhu Sun, Lei Ge, Yicong Li, Wenbin Hendon, Christopher H Li, Ju Dinca, Mircea Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu) |
| title | Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu) |
| title_full | Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu) |
| title_fullStr | Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu) |
| title_full_unstemmed | Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu) |
| title_short | Signature of Metallic Behavior in the Metal–Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu) |
| title_sort | signature of metallic behavior in the metal organic frameworks m₃ hexaiminobenzene ₂ m ni cu |
| url | http://hdl.handle.net/1721.1/118371 https://orcid.org/0000-0002-5645-7531 https://orcid.org/0000-0002-7841-8058 https://orcid.org/0000-0002-1262-1264 |
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