Conformation of bis-nitroxide polarizing agents by multi-frequency EPR spectroscopy

The chemical structure of polarizing agents critically determines the efficiency of dynamic nuclear polarization (DNP). For cross-effect DNP, biradicals are the polarizing agents of choice and the interaction and relative orientation of the two unpaired electrons should be optimal. Both parameters a...

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Bibliographic Details
Main Authors: Gast, Peter, Soetbeer, Janne Marie, Walish, Joseph John, Zhao, Yanchuan, George, Christy, Yang, Chen, Swager, Timothy M, Griffin, Robert Guy, Mathies, Guinevere
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: Royal Society of Chemistry (RSC) 2018
Online Access:http://hdl.handle.net/1721.1/119204
https://orcid.org/0000-0001-9210-2394
https://orcid.org/0000-0002-2073-2343
https://orcid.org/0000-0003-1589-832X
https://orcid.org/0000-0002-2719-0743