Aza Diels-Alder Reactions of Nitriles, N, N-Dimethylhydrazones, and Oximino Ethers. Application in Formal [2 + 2 + 2] Cycloadditions for the Synthesis of Pyridines

Aza Diels-Alder Reactions of Nitriles, N, N-Dimethylhydrazones, and Oximino Ethers. Application in Formal [2 + 2 + 2] Cycloadditions for the Synthesis of Pyridines

Metal-free, formal [2 + 2 + 2] cycloaddition st rategies for the synthesis of polycyclic pyridine derivatives are described. The overall transformation proceeds via a two-stage pericyclic cascade mechanism. In the first step, an intramolecular propargylic ene reaction generates a vinyl-allene that...

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Bibliographic Details
Main Authors: Hamzik, Philip Jonathan, Goutierre, Anne-Sophie, Sakai, Takeo, Danheiser, Rick Lane
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/119382
https://orcid.org/0000-0003-4681-8310
https://orcid.org/0000-0002-9812-206X

Internet

http://hdl.handle.net/1721.1/119382
https://orcid.org/0000-0003-4681-8310
https://orcid.org/0000-0002-9812-206X

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