Strong Electronic Coupling of Molecular Sites to Graphitic Electrodes via Pyrazine Conjugation

Strong Electronic Coupling of Molecular Sites to Graphitic Electrodes via Pyrazine Conjugation

Glassy carbon electrodes were functionalized with redox-active moieties by condensation of o-phenylenediamine derivatives with o-quinone sites native to graphitic carbon surfaces. Electrochemical and spectroscopic investigations establish that these graphite-conjugated catalysts (GCCs) exhibit stron...

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Bibliographic Details
Main Authors: Zhang, Guanghui, Miller, Jeffrey T., Jackson, Megan, Oh, Seokjoon, Kaminsky, Corey Jarin, Chu, Sterling B, Surendranath, Yogesh
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2018
Online Access:http://hdl.handle.net/1721.1/119426
https://orcid.org/0000-0002-7978-5212
https://orcid.org/0000-0002-8980-5213
https://orcid.org/0000-0003-4783-4734
https://orcid.org/0000-0003-1016-3420

Internet

http://hdl.handle.net/1721.1/119426
https://orcid.org/0000-0002-7978-5212
https://orcid.org/0000-0002-8980-5213
https://orcid.org/0000-0003-4783-4734
https://orcid.org/0000-0003-1016-3420

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