Strong Electronic Coupling of Molecular Sites to Graphitic Electrodes via Pyrazine Conjugation

Glassy carbon electrodes were functionalized with redox-active moieties by condensation of o-phenylenediamine derivatives with o-quinone sites native to graphitic carbon surfaces. Electrochemical and spectroscopic investigations establish that these graphite-conjugated catalysts (GCCs) exhibit stron...

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Detalhes bibliográficos
Principais autores: Zhang, Guanghui, Miller, Jeffrey T., Jackson, Megan, Oh, Seokjoon, Kaminsky, Corey Jarin, Chu, Sterling B, Surendranath, Yogesh
Outros Autores: Massachusetts Institute of Technology. Department of Chemistry
Formato: Artigo
Idioma:en_US
Publicado em: American Chemical Society (ACS) 2018
Acesso em linha:http://hdl.handle.net/1721.1/119426
https://orcid.org/0000-0002-7978-5212
https://orcid.org/0000-0002-8980-5213
https://orcid.org/0000-0003-4783-4734
https://orcid.org/0000-0003-1016-3420