Strong Electronic Coupling of Molecular Sites to Graphitic Electrodes via Pyrazine Conjugation
Glassy carbon electrodes were functionalized with redox-active moieties by condensation of o-phenylenediamine derivatives with o-quinone sites native to graphitic carbon surfaces. Electrochemical and spectroscopic investigations establish that these graphite-conjugated catalysts (GCCs) exhibit stron...
Main Authors: | Zhang, Guanghui, Miller, Jeffrey T., Jackson, Megan, Oh, Seokjoon, Kaminsky, Corey Jarin, Chu, Sterling B, Surendranath, Yogesh |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2018
|
Online Access: | http://hdl.handle.net/1721.1/119426 https://orcid.org/0000-0002-7978-5212 https://orcid.org/0000-0002-8980-5213 https://orcid.org/0000-0003-4783-4734 https://orcid.org/0000-0003-1016-3420 |
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