Syntheses of Molybdenum Oxo Alkylidene Complexes through Addition of Water to an Alkylidyne Complex
Addition of one equiv of water to Mo(CAr)[OCMe(CF 3 ) 2 ] 3 (1,2 - dimethoxyethane) ( 2, Ar = o-(OMe)C 6 H 4 ) in the presence of PPhMe 2 leads to formation of Mo(O)(CHAr)[OCMe(CF 3 ) 2 ] 2 (PPhMe 2 ) ( 3(PPhMe 2 ) ) in 3 4 % yield. Addition of one equiv of water alone to 2 produces the dimeric a...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2019
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| Online Access: | http://hdl.handle.net/1721.1/120475 https://orcid.org/0000-0001-5827-3552 |