Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity

Sulfur monoxide (SO) is a highly reactive molecule and thus, eludes bulk isolation. We report here on synthesis and reactivity of a molecular precursor for SO generation, namely 7-sulfin-ylamino-7-azadibenzonorbornadiene (1). This compound has been shown to fragment readily driven by dinitrogen expu...

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Main Authors: Martin-Drumel, Marie-Aline, McCarthy, Michael C., Patterson, David, Joost, Maximilian G, Nava, Matthew Jordan, Transue, Wesley, Cummins, Christopher C
其他作者: Massachusetts Institute of Technology. Department of Chemistry
格式: 文件
出版: National Academy of Sciences (U.S.) 2019
在线阅读:http://hdl.handle.net/1721.1/120567
https://orcid.org/0000-0002-9239-7505
https://orcid.org/0000-0001-7445-5663
https://orcid.org/0000-0003-2568-3269