A Synthetic Model of Enzymatic [Fe₄S₄]–Alkyl Intermediates
Although alkyl complexes of [Fe₄S₄] clusters have been invoked as intermediates in a number of enzymatic reactions, obtaining a detailed understanding of their reactivity patterns and electronic structures has been difficult owing to their transient nature. To address this challenge, we herein repor...
Main Authors: | , , , |
---|---|
Other Authors: | |
Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS)
2019
|
Online Access: | https://hdl.handle.net/1721.1/122277 |