A Synthetic Model of Enzymatic [Fe₄S₄]–Alkyl Intermediates

Although alkyl complexes of [Fe₄S₄] clusters have been invoked as intermediates in a number of enzymatic reactions, obtaining a detailed understanding of their reactivity patterns and electronic structures has been difficult owing to their transient nature. To address this challenge, we herein repor...

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Bibliographic Details
Main Authors: Ye, Mengshan, Thompson, Niklas B., Brown, Alexandra C., Suess, Daniel L. M.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: American Chemical Society (ACS) 2019
Online Access:https://hdl.handle.net/1721.1/122277