A Synthetic Model of Enzymatic [Fe₄S₄]–Alkyl Intermediates
Although alkyl complexes of [Fe₄S₄] clusters have been invoked as intermediates in a number of enzymatic reactions, obtaining a detailed understanding of their reactivity patterns and electronic structures has been difficult owing to their transient nature. To address this challenge, we herein repor...
Main Authors: | Ye, Mengshan, Thompson, Niklas B., Brown, Alexandra C., Suess, Daniel L. M. |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS)
2019
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Online Access: | https://hdl.handle.net/1721.1/122277 |
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